LITHIUM ION BATTERY SCRAP TREATMENT METHOD
DRIVE
February 6, 2020
The present invention relates to a method for treating lithium ion battery scrap containing Li, Ni, Co, Mn, Al, Cu and Fe, the method comprising carrying out a calcination step, a crushing step and a sieving step in this order, and after the steps, the method comprising: a leaching step of leaching the lithium ion battery scrap by adding it to an acidic solution to leave at least a part of Cu as a solid; a Fe/Al removal step comprising allowing a leached solution obtained in the leaching step to pass through a Fe removal process for separating and removing Fe by addition of an oxidizing agent and an Al removal process for separating and removing a part of Al by neutralization in any order; an Al/Mn extraction step of extracting and removing a residue of Al and Mn from a separated solution obtained in the Fe/Al removal step by solvent extraction; a Co recovery step of extracting and back-extracting Co from a first extracted solution obtained in the Al/Mn extraction step by solvent extraction and recovering the Co by electrolytic winning; a Ni recovery step of extracting and back-extracting, by solvent extraction, a part of Ni from a second extracted solution obtained by the solvent extraction in the Co recovery step and recovering the Ni by electrolytic winning; a Li concentration step of extracting and back-extracting, by solvent extraction, a residue of Ni and Li from a third extracted solution obtained by the solvent extraction in the Ni recovery step and repeating the operations of the extracting and the back-extracting to concentrate Li; and a Li recovery step of carbonating Li in a Li concentrated solution obtained in the Li concentration step to recover the Li as lithium carbonate.
Discussion in the ATmosphere