POSITIVE ELECTRODE ACTIVE MATERIAL FOR SECONDARY BATTERY AND LITHIUM SECONDARY BATTERY COMPRISING SAME
DRIVE
January 1, 2025
Provided is a positive electrode active material for a secondary battery, which is a lithium composite transition metal oxide containing nickel, cobalt, and manganese and having a nickel content for 60 mol% or more, based on metals (M) excluding lithium, and is in the form of single particles having an average particle diameter (D50) of 1 to 10 µm, wherein a 100-nm region extending from the surface toward the center of a particle of the lithium composite transition metal oxide has crystal structures of a Fd3M and a Fm3m space group, and a phase ratio (Fd3M/Fm3m), which is a ratio of the maximum straight length of portions occupied by the crystal structure of the Fd3M space group and the crystal structure of the Fm3m space group, is 0.2 to 0.7, as determined in a cross-sectional image file of the particle surface part of the lithium composite transition metal oxide particle, which is obtained using transmission electron microscopy (TEM).
Discussion in the ATmosphere