Nonaqueous Electrolyte Solution and Nonaqueous-Electrolytic-Solution Battery

Provided is a non-aqueous electrolyte solution which can reduce the amount of gas generation during initial conditioning of a non-aqueous electrolyte battery. This non-aqueous electrolyte solution is for a non-aqueous electrolyte battery which includes a positive electrode and a negative electrode that are capable of occluding and releasing metal ions, and the non-aqueous electrolyte solution is characterized by containing an alkali metal salt, a non-aqueous solvent, at least one Si—O structure-containing compound represented by Formula (A) or (B), and a compound represented by Formula (α).