NICKEL-CONTAINING POSITIVE ELECTRODE SLURRIES HAVING REDUCED OR ELIMINATED GELATION AND HIGH-ENERGY-DENSITY POSITIVE ELECTRODES FOR ELECTROCHEMICAL CELLS

An electrode precursor or slurry according to various aspects of the present disclosure includes a blended electroactive material and a binder solution. The blended electroactive material includes a first electroactive material and a second electroactive material. The first electroactive material includes nickel. The first electroactive material is selected from the group consisting of LiNiCoMnOwhere x is greater than 0.6, LiNiCoAlOwhere x is greater than 0.6, LiNiCoMnAlOwhere x is greater than 0.6, or any combination thereof. The second electroactive material includes a phosphor-olivine compound at less than or equal to about 30 weight percent of the blended electroactive material. The binder solution including a polymeric binder and a solvent including N-methyl-2-pyrrolidone. In various aspects, the present disclosure provides a high-nickel-content positive electrode formed from the slurry. In various aspects, the present disclosure provides an electrochemical cell including the positive electrode and a lithium metal negative electrode.