AL-DOPED SHEET LLZO COMPOSITE SOLID-STATE ELECTROLYTE AND PREPARATION METHOD AND APPLICATION THEREOF

A preparation of solid-state electrolytes, in particular to an Al-doped sheet LLZO composite solid-state electrolyte and a preparation method and application thereof. The composite solid-state electrolyte includes Al ions, an LLZO solid-state electrolyte and a polymer substrate. The Al is doped in the LLZO solid-state electrolyte in a sheet structure, and the LLZO solid-state electrolyte is dispersed in the polymer substrate. The composite solid-state electrolyte has good flexibility, and has higher ionic conductivity than the granular doped composite solid-state electrolyte since the sheet LLZO provides a fast conduction channel for lithium ions. In addition, the preparation method is simple, suitable for large-scale production, and environmentally friendly since no toxic solvent is used in the preparation process.