Pouch Film Laminate, Pouch Type Battery Case, and Pouch Type Secondary Battery

A pouch film laminate for preparing a pouch type battery case accommodating an electrode assembly is provided. The pouch film laminate includes a sealant layer formed of a first polymer as an innermost layer, a surface protection layer formed of a second polymer as an outermost layer, an aluminum alloy thin film having a grain size of 10 μm to 13 μm, and a gas barrier layer laminated between the surface protection layer and the sealant layer, wherein the gas barrier layer has a thickness of 50 μm to 70 μm, and the sealant layer has a thickness of 70 μm to 100 μm.