ELECTRODE SEPARATOR WITH PIEZOELECTRIC LAYER FOR IN-STACK PRESSURE SENSING AND DENDRITE CLEANING

Presented are electrochemical devices with in-stack pressure sensors, methods for making/using such devices, and battery cells with electrode stacks having an electrode separator assembly with a piezoelectric layer for in-stack pressure sensing and dendrite cleaning. An electric machine, such as a lithium-class secondary battery cell for example, includes a device housing with an ion-conducting electrolyte located inside the device housing. A stack of working electrodes is also located inside the device housing, in electrochemical contact with the electrolyte. At least one electrode separator assembly is located inside the device housing, interposed between a neighboring pair of the working electrodes. The electrode separator assembly includes a pair of separator layers that transmit therethrough the ions of the electrolyte, and a piezoelectric layer that is interposed between the two separator layers. The piezoelectric layer outputs an electrical signal in response to deformation of one or both of the neighboring working electrodes.