Method for performing enrichment of an electrode of an electrochemical device with ionic species

Method for an electrochemical device electrode enrichment, with ionic-species, including steps of: providing a substrate with at least one stack including: a first current-collector covering at least part of the substrate, first electrode covering at least part of the first current-collector, the first electrode being in electric contact with the first current-collector, protective layer totally covering the first electrode and at least part of the first current-collector, the protective layer being electrically insulating and ionically conducting; immersing in an electrolytic solution: the substrate provided with stack, counter-electrode made from conducting material, the electrolytic solution including at least one ionic-species salt and/or counter-electrode including ionic-species, applying electric voltage or current, with voltage or current generator, between first current-collector and counter-electrode making the ionic-species migrate to the first electrode and enrich the first electrode with ionic-species, depositing a second electrode on the protective layer after enrichment of the first electrode with ionic-species.