NICKEL-CONTAINING COMPOSITE HYDROXIDE AND PRODUCTION PROCESS THEREFOR, POSITIVE-ELECTRODE ACTIVE MATERIAL FOR A NONAQUEOUS-ELECTROLYTE SECONDARY BATTERY AND PRODUCTION PROCESS THEREFOR, AND NONAQUEOUS-ELECTROLYTE SECONDARY BATTERY
DRIVE
November 9, 2017
Provided is a nickel-containing composite hydroxide that is a precursor of a positive-electrode active material with which a nonaqueous-electrolyte secondary battery having a low irreversible capacity and a high energy density can be configured. An aqueous alkaline aqueous solution and a complexing agent are added to an mixed aqueous solution including at least nickel and cobalt to regulate the pH (measured at a reference liquid temperature of 25° C.) of this mixed aqueous solution to 11.0 to 13.0, the ammonium concentration to 4 to 15 g/L, and the reaction temperature to 20° C. to 45° C. Using stirring blades having an inclination angle of 20° to 60° with respect to a horizontal plane, the mixture is stirred to conduct a crystallization reaction under such conditions that when the nickel-containing composite hydroxide to be obtained is roasted in air at 800° C. for 2 hours, the roasted composite hydroxide has a BET value of 12 to 50 m/g. Thus a nickel-containing composite hydroxide expressed by NiCoAlM(OH) (where, 0
Discussion in the ATmosphere