MTHOD FOR PREPARING COBALT-FREE LAYERED CATHODE MATERIAL BY LI+/H+ EXCHANGE

Provided is a method for preparing a cobalt-free layered cathode material by Li/H exchange, including adding a metal sulfate solution, a precipitant solution, and a complexing agent solution dropwise into an aqueous ammonia solution to obtain a mixed solution, and subjecting the mixed solution to precipitation complexation to obtain a hydroxide precursor; and mixing the hydroxide precursor with a lithium source to obtain a mixture, and subjecting the mixture to pre-sintering and crystallization in sequence to obtain the cobalt-free layered cathode material, a temperature for the pre-sintering being less than a temperature for the crystallization, where metal sulfates include at least two selected from the group consisting of non-cobalt transition metal sulfates.